Issue 50, 2015
From the journal:

Chemical Communications

Direct accessibility of mixed-metal (iii/ii) acid sites through the rational synthesis of porous metal carboxylates†

S. Wongsakulphasatch,ab   F. Nouar,*a   J. Rodriguez,c   L. Scott,a   C. Le Guillouzer,d   T. Devic,a   P. Horcajada,a   J.-M. Grenèche,e   P. L. Llewellyn,c   A. Vimont,d   G. Clet,d   M. Daturid  and  C. Serre*a  

* Corresponding authors

a Institut Lavoisier (CNRS UMR 8180), Université de Versailles St-Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France
E-mail: farid.nouar@uvsq.fr, christian.serre@uvsq.fr

b Department of Chemical Engineering, Faculty of Engineering and Industrial Technology Silpakorn University, Nakhon Pathom 73000, Thailand

c Aix-Marseille Univ., CNRS, Laboratoire MADIREL (UMR 7246), Campus de Saint Jérôme, 13397, Marseille Cedex 20, France

d Laboratoire Catalyse et Spectrochimie, ENSICAEN, Université de Caen Basse-Normandie, CNRS, 6 Bd Maréchal Juin, 14050 Caen, France

e Institut des Molécules et des Matériaux du Mans (CNRS UMR 6283), Université du Maine, 72085 Le Mans, France

Abstract

The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, 57Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.

Graphical abstract: Direct accessibility of mixed-metal (iii/ii) acid sites through the rational synthesis of porous metal carboxylates

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Article information

DOI
https://doi.org/10.1039/C5CC02550H
Article type
Communication
Submitted
27 Mar 2015
Accepted
14 May 2015
First published
14 May 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 10194-10197

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Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

S. Wongsakulphasatch, F. Nouar, J. Rodriguez, L. Scott, C. Le Guillouzer, T. Devic, P. Horcajada, J.-M. Grenèche, P. L. Llewellyn, A. Vimont, G. Clet, M. Daturi and C. Serre, Chem. Commun., 2015, 51, 10194 DOI: 10.1039/C5CC02550H

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