Issue 48, 2015
From the journal:

Chemical Communications

“Click” post-functionalization of a metal–organic framework for engineering active single-site heterogeneous Ru(iii) catalysts†

Suntao Wu,a   Liyu Chen,a   Biaolin Yina  and  Yingwei Li*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: liyw@scut.edu.cn

Abstract

We present a general strategy for incorporating π-conjugated NNN-chelators (e.g., terpyridyl moiety) into a porous metal–organic framework (MOF) MIL-101(Cr) by using the “click” post-functionalization. The functionalized MOF could be used as a platform for metalation to yield highly active and stable single-site heterogeneous metal (e.g., Ru(III)) catalysts.

Graphical abstract: “Click” post-functionalization of a metal–organic framework for engineering active single-site heterogeneous Ru(iii) catalysts

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Article information

DOI
https://doi.org/10.1039/C5CC02741A
Article type
Communication
Submitted
02 Apr 2015
Accepted
15 May 2015
First published
15 May 2015

Chem. Commun., 2015,51, 9884-9887

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“Click” post-functionalization of a metal–organic framework for engineering active single-site heterogeneous Ru(III) catalysts

S. Wu, L. Chen, B. Yin and Y. Li, Chem. Commun., 2015, 51, 9884 DOI: 10.1039/C5CC02741A

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