Determination of magnetic anisotropy in a multinuclear TbIII-based single-molecule magnet

Xing-Cai Huang; Veacheslav Vieru; Liviu F. Chibotaru; Wolfgang Wernsdorfer; Shang-Da Jiang; Xin-Yi Wang

doi:10.1039/C5CC03089G

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Determination of magnetic anisotropy in a multinuclear Tb^III-based single-molecule magnet†

Xing-Cai Huang,^a Veacheslav Vieru,^b Liviu F. Chibotaru,*^b Wolfgang Wernsdorfer,^c Shang-Da Jiang*^d and Xin-Yi Wang*^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: wangxy66@nju.edu.cn

^b Theory of Nanomaterials Group and INPAC – Institute of Nanoscale Physics and Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Heverlee, Belgium
E-mail: liviu.Chibotaru@chem.kuleuven.be

^c Institut Néel, CNRS & UJF BP 166, Grenoble Cedex 9, France

^d LNCMI-CNRS 25, rue des Martyrs–BP 166, Grenoble Cedex 9, France
E-mail: jiang@lncmi.cnrs.fr

Abstract

Magneto-structural relationships were studied experimentally and theoretically for two enantiomorphic tetranuclear [CuTb]₂ SMMs. For the first time, the determination of the magnetic anisotropy axis of an individual magnetic ion, Tb³⁺, was achieved in a polynuclear Tb³⁺-based SMM.

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DOI: https://doi.org/10.1039/C5CC03089G
Article type: Communication
Submitted: 14 Apr 2015
Accepted: 06 May 2015
First published: 06 May 2015

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Chem. Commun., 2015,51, 10373-10376

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Determination of magnetic anisotropy in a multinuclear Tb^III-based single-molecule magnet

X. Huang, V. Vieru, L. F. Chibotaru, W. Wernsdorfer, S. Jiang and X. Wang, Chem. Commun., 2015, 51, 10373 DOI: 10.1039/C5CC03089G

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