Issue 56, 2015

Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

Abstract

A facile and efficient catalytic system based on a mesostructured ceria-supported gold (Au/meso-CeO2) catalyst was developed for the synthesis of various aromatic azo compounds by the reductive coupling of the corresponding nitroaromatics, using CO as the sole deoxygenative reagent, under additive-free and mild reaction conditions.

Graphical abstract: Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

Supplementary files

Article information

Article type
Communication
Submitted
15 Apr 2015
Accepted
29 May 2015
First published
01 Jun 2015

Chem. Commun., 2015,51, 11217-11220

Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

H. Li, X. Liu, Q. Zhang, S. Li, Y. Liu, H. He and Y. Cao, Chem. Commun., 2015, 51, 11217 DOI: 10.1039/C5CC03134F

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