“Half-sandwich” YbIII single-ion magnets with metallacrowns

Quan-Wen Li; Jun-Liang Liu; Jian-Hua Jia; Yan-Cong Chen; Jiang Liu; Long-Fei Wang; Ming-Liang Tong

doi:10.1039/C5CC03389F

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“Half-sandwich” Yb^III single-ion magnets with metallacrowns†

Quan-Wen Li,^a Jun-Liang Liu,

^a Jian-Hua Jia,*^a Yan-Cong Chen,^a Jiang Liu,^a Long-Fei Wang^a and Ming-Liang Tong*^a

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* Corresponding authors

^a MOE Key Lab of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China
E-mail: jiajh3@mail.sysu.edu.cn, tongml@mail.sysu.edu.cn

Abstract

The first “half-sandwich” Yb^III single-ion magnets (SIMs) based on [12-MC_Zn(II₎-4] are reported, in which the central ytterbium ion is coordinated by YbO₈ geometry in D_4d symmetry. The anisotropic barrier is extracted from the analysis of static, dynamic magnetism and emission spectrum offering an insight into the magneto-optical correlation.

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Article information

DOI: https://doi.org/10.1039/C5CC03389F
Article type: Communication
Submitted: 24 Apr 2015
Accepted: 13 May 2015
First published: 14 May 2015

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Chem. Commun., 2015,51, 10291-10294

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“Half-sandwich” Yb^III single-ion magnets with metallacrowns

Q. Li, J. Liu, J. Jia, Y. Chen, J. Liu, L. Wang and M. Tong, Chem. Commun., 2015, 51, 10291 DOI: 10.1039/C5CC03389F

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Chemical Communications