Issue 59, 2015
From the journal:

Chemical Communications

Iron-catalyzed amination of alcohols assisted by Lewis acid†

Hui-Jie Pan,a   Teng Wei Nga  and  Yu Zhao*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Republic of Singapore
E-mail: zhaoyu@nus.edu.sg

Abstract

An efficient Lewis acid-assisted, iron-catalyzed amination of alcohols using borrowing hydrogen methodology was developed. In particular, silver fluoride was identified to be a highly effective additive to overcome the low efficiency in the amination of secondary alcohols catalyzed by Knölker's complex.

Graphical abstract: Iron-catalyzed amination of alcohols assisted by Lewis acid

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Article information

DOI
https://doi.org/10.1039/C5CC03399C
Article type
Communication
Submitted
24 Apr 2015
Accepted
17 Jun 2015
First published
17 Jun 2015

Chem. Commun., 2015,51, 11907-11910

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Iron-catalyzed amination of alcohols assisted by Lewis acid

H. Pan, T. W. Ng and Y. Zhao, Chem. Commun., 2015, 51, 11907 DOI: 10.1039/C5CC03399C

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