Issue 63, 2015
From the journal:

Chemical Communications

[Cp*RhCl2]2: mechanosynthesis and applications in C–H bond functionalisations under ball-milling conditions†

José G. Hernández*a  and  Carsten Bolm*a  

* Corresponding authors

a Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, D-52074 Aachen, Germany
E-mail: carsten.bolm@oc.rwth-aachen.de
Fax: +49 241 80 92 391
Tel: +49 24 80 94 675

Abstract

A mechanochemical synthesis of [Cp*RhCl2]2 has been developed. Under LAG conditions the organometallic complex can be prepared in a shorter reaction time compared to the standard solution-based protocol. The obtained Rh(III) dimer is then applicable as catalyst in subsequent solvent-free mechanochemical C–H bond functionalisations of 2-phenylpyridine.

Graphical abstract: [Cp*RhCl2]2: mechanosynthesis and applications in C–H bond functionalisations under ball-milling conditions

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Article information

DOI
https://doi.org/10.1039/C5CC04423E
Article type
Communication
Submitted
29 May 2015
Accepted
26 Jun 2015
First published
26 Jun 2015

Chem. Commun., 2015,51, 12582-12584

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[Cp*RhCl2]2: mechanosynthesis and applications in C–H bond functionalisations under ball-milling conditions

J. G. Hernández and C. Bolm, Chem. Commun., 2015, 51, 12582 DOI: 10.1039/C5CC04423E

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