Issue 59, 2015

Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

Abstract

We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature.

Graphical abstract: Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

Supplementary files

Article information

Article type
Communication
Submitted
02 Jun 2015
Accepted
18 Jun 2015
First published
18 Jun 2015

Chem. Commun., 2015,51, 11864-11867

Author version available

Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

X. Wu, C. Meng, X. Yuan, X. Jia, X. Qian and J. Ye, Chem. Commun., 2015, 51, 11864 DOI: 10.1039/C5CC04527D

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