Issue 61, 2015

Design of a hyperpolarized 15N NMR probe that induces a large chemical-shift change upon binding of calcium ions

Abstract

Ca2+ is a fundamental metal ion for physiological functioning. Therefore, molecular probes for Ca2+ analysis are required. Recently, a hyperpolarized NMR probe has emerged as a promising tool. Here, we report a new design of a hyperpolarized NMR probe for Ca2+, which showed a large chemical shift change upon binding to Ca2+ and was applied for Ca2+ sensing in a hyperpolarized state.

Graphical abstract: Design of a hyperpolarized 15N NMR probe that induces a large chemical-shift change upon binding of calcium ions

Supplementary files

Article information

Article type
Communication
Submitted
04 Jun 2015
Accepted
26 Jun 2015
First published
03 Jul 2015

Chem. Commun., 2015,51, 12290-12292

Author version available

Design of a hyperpolarized 15N NMR probe that induces a large chemical-shift change upon binding of calcium ions

R. Hata, H. Nonaka, Y. Takakusagi, K. Ichikawa and S. Sando, Chem. Commun., 2015, 51, 12290 DOI: 10.1039/C5CC04597E

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