The microwave-assisted solvothermal synthesis of a crystalline two-dimensional covalent organic framework with high CO2 capacity

Hao Wei; Shuangzhi Chai; Nantao Hu; Zhi Yang; Liangming Wei; Lin Wang

doi:10.1039/C5CC04680G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

The microwave-assisted solvothermal synthesis of a crystalline two-dimensional covalent organic framework with high CO₂ capacity†

Hao Wei,*^a Shuangzhi Chai,^a Nantao Hu,^a Zhi Yang,*^a Liangming Wei*^a and Lin Wang^b

Author affiliations

* Corresponding authors

^a Key Laboratory for Thin Film and Microfabrication Technology of Ministry of Education, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
E-mail: haowei@sjtu.edu.cn, zhiyang@sjtu.edu.cn, lmwei@sjtu.edu.cn

^b Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Miyagi 980-8578, Japan

Abstract

We report the synthesis of a two-dimensional enamine-linked covalent organic framework (COF) using a rapid microwave-assisted solvothermal method in significantly less time and high yield under a relatively low temperature. This COF was found to have a high crystallinity, high stability, high BET surface area, and a high CO₂ capacity and adsorption selectivity of CO₂/N₂.

Download options Please wait...

Supplementary files

Supplementary information PDF (585K)

Article information

DOI: https://doi.org/10.1039/C5CC04680G
Article type: Communication
Submitted: 07 Jun 2015
Accepted: 26 Jun 2015
First published: 26 Jun 2015

Download Citation

Chem. Commun., 2015,51, 12178-12181

Permissions

Request permissions

The microwave-assisted solvothermal synthesis of a crystalline two-dimensional covalent organic framework with high CO₂ capacity

H. Wei, S. Chai, N. Hu, Z. Yang, L. Wei and L. Wang, Chem. Commun., 2015, 51, 12178 DOI: 10.1039/C5CC04680G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications