Issue 82, 2015

Triply cyclometalated trinuclear iridium(iii) and trinuclear palladium(ii) complexes with a tri-mesoionic carbene ligand

Abstract

The first example of a triply cyclometalated homopolynuclear tri-IrIII complex with additional carbene donors is presented. Cooperative catalysis and the interplay between homogenous and heterogeneous catalyses are discussed for the tri-IrIII complex and a related non-cyclometalated tri-PdII complex.

Graphical abstract: Triply cyclometalated trinuclear iridium(iii) and trinuclear palladium(ii) complexes with a tri-mesoionic carbene ligand

Supplementary files

Article information

Article type
Communication
Submitted
03 Jul 2015
Accepted
28 Jul 2015
First published
29 Jul 2015

Chem. Commun., 2015,51, 15106-15109

Triply cyclometalated trinuclear iridium(III) and trinuclear palladium(II) complexes with a tri-mesoionic carbene ligand

R. Maity, A. Mekic, M. van der Meer, A. Verma and B. Sarkar, Chem. Commun., 2015, 51, 15106 DOI: 10.1039/C5CC05506G

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