Issue 72, 2015

Switching of inherent chirality driven by self-assembly

Abstract

Dynamic chirality of iminoresorcin[4]arenes that originates from regioselective and diastereoselective keto–enol tautomerisation was switched by non-covalent interactions with achiral molecules, as demonstrated by experimental electronic circular dichroism (ECD) spectra supported by TD DFT calculations.

Graphical abstract: Switching of inherent chirality driven by self-assembly

Supplementary files

Article information

Article type
Communication
Submitted
10 Jul 2015
Accepted
22 Jul 2015
First published
03 Aug 2015

Chem. Commun., 2015,51, 13799-13801

Author version available

Switching of inherent chirality driven by self-assembly

H. Jędrzejewska, M. Kwit and A. Szumna, Chem. Commun., 2015, 51, 13799 DOI: 10.1039/C5CC05728K

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