Issue 83, 2015
From the journal:

Chemical Communications

A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons†

Dongmei Wang,a   Bing Liu,a   Shuo Yao,a   Tao Wang,a   Guanghua Li,a   Qisheng Huoa  and  Yunling Liu*a  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: yunling@jlu.edu.cn
Fax: +86-431-85168624
Tel: +86-431-85168614

Abstract

By using the supermolecular building block (SBB) strategy, a polyhedron-based metal–organic framework (PMOF), which features three types of cages with multiple sizes and shapes, has been synthesized. It exhibits high performance for CO2 capture (170 cm3 g−1 at 273 K under 1 bar) and selectivity of CO2/CH4 (9.4) and C3H8/CH4 (271.5).

Graphical abstract: A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons

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Article information

DOI
https://doi.org/10.1039/C5CC06162H
Article type
Communication
Submitted
23 Jul 2015
Accepted
21 Aug 2015
First published
21 Aug 2015

Chem. Commun., 2015,51, 15287-15289

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A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons

D. Wang, B. Liu, S. Yao, T. Wang, G. Li, Q. Huo and Y. Liu, Chem. Commun., 2015, 51, 15287 DOI: 10.1039/C5CC06162H

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