Issue 84, 2015
From the journal:

Chemical Communications

Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition†

Long-Fei Wang,a   Jiang-Zhen Qiu,a   Jun-Liang Liu, ORCID logo *a   Yan-Cong Chen,a   Jian-Hua Jia,*a   Jesús Jover,b   Eliseo Ruiz*b  and  Ming-Liang Tong*a  

* Corresponding authors

a Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China
E-mail: ljliang1987@gmail.com, jiajh3@mail.sysu.edu.cn, tongml@mail.sysu.edu.cn

b Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, E-08028 Barcelona, Spain
E-mail: eliseo.ruiz@qi.ub.es

Abstract

The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation.

Graphical abstract: Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

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Article information

DOI
https://doi.org/10.1039/C5CC07073B
Article type
Communication
Submitted
22 Aug 2015
Accepted
03 Sep 2015
First published
03 Sep 2015

Chem. Commun., 2015,51, 15358-15361

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Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

L. Wang, J. Qiu, J. Liu, Y. Chen, J. Jia, J. Jover, E. Ruiz and M. Tong, Chem. Commun., 2015, 51, 15358 DOI: 10.1039/C5CC07073B

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