Issue 94, 2015

Controlled generation of highly saddled (porphyrinato)iron(iii) iodide, tri-iodide and one-electron oxidized complexes

Abstract

For the first time, three iron(III) porphyrinato complexes have been synthesized selectively by varying the iodine concentration in the reaction mixture which eventually forms both five and six coordinate complexes with iodide and/or tri-iodide as axial ligands. Combined analysis using single crystal X-ray structure determination, and Mössbauer, 1H NMR and EPR studies as well as VT magnetic studies has revealed the admixed-intermediate (iodo complex), pure intermediate (tri-iodide complex) and high-spin (1e-oxidized complex) states of iron.

Graphical abstract: Controlled generation of highly saddled (porphyrinato)iron(iii) iodide, tri-iodide and one-electron oxidized complexes

Supplementary files

Article information

Article type
Communication
Submitted
24 Aug 2015
Accepted
19 Sep 2015
First published
21 Sep 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 16790-16793

Controlled generation of highly saddled (porphyrinato)iron(III) iodide, tri-iodide and one-electron oxidized complexes

D. Sahoo and S. P. Rath, Chem. Commun., 2015, 51, 16790 DOI: 10.1039/C5CC07111A

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