Issue 2, 2016
From the journal:

Chemical Communications

A triacontanuclear [Zn12Dy18] cluster: a ring of [Dy4] cubes†

Nikoleta Stavgianoudaki,a   Milosz Siczek,b   Tadeusz Lis,b   Ross Inglis*c  and  Constantinos J. Milios*a  

* Corresponding authors

a Department of Chemistry, The University of Crete, Voutes, Herakleion, Greece
E-mail: komil@uoc.gr

b Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw, Poland

c EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, EH9 3FJ Edinburgh, UK
E-mail: r.inglis@ed.ac.uk

Abstract

The reaction between Dy(NO3)3·6H2O, Zn(OAc)2·4H2O, salicylaldehyde and 2-amino-isobutyric acid, in MeOH in the presence of NEt3 under solvothermal conditions, led to the isolation of the triacontanuclear mixed-metal cluster [ZnII12DyIII18(OH)30(L)12(sal)6(OAc)6(NO3)3(H2O)6](NO3)3·12MeOH·5H2O (1·12MeOH·5H2O), which displays frequency- and temperature-dependent out-of-phase magnetic susceptibility signals.

Graphical abstract: A triacontanuclear [Zn12Dy18] cluster: a ring of [Dy4] cubes

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Article information

DOI
https://doi.org/10.1039/C5CC07243C
Article type
Communication
Submitted
28 Aug 2015
Accepted
22 Oct 2015
First published
22 Oct 2015

Chem. Commun., 2016,52, 343-345

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A triacontanuclear [Zn12Dy18] cluster: a ring of [Dy4] cubes

N. Stavgianoudaki, M. Siczek, T. Lis, R. Inglis and C. J. Milios, Chem. Commun., 2016, 52, 343 DOI: 10.1039/C5CC07243C

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