Issue 97, 2015
From the journal:

Chemical Communications

Liquid marbles as a micro-reactor for efficient radical alternating copolymerization of diene monomer and oxygen†

E. Sato,*a   M. Yuri,a   S. Fujii,b   T. Nishiyama,a   Y. Nakamurab  and  H. Horibea  

* Corresponding authors

a Department of Applied Chemistry and Bioengineering, Graduate School of Engineering, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: sato@a-chem.eng.osaka-cu.ac.jp

b Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan

Abstract

Liquid marbles have been shown to be a novel micro-reactor to synthesize polyperoxides by the radical alternating copolymerization of the 1,3-diene monomer with oxygen in a good yield. Oxygen gas is effectively absorbed as a comonomer by the large and permeable gas–liquid interface of the liquid marbles.

Graphical abstract: Liquid marbles as a micro-reactor for efficient radical alternating copolymerization of diene monomer and oxygen

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Article information

DOI
https://doi.org/10.1039/C5CC07421E
Article type
Communication
Submitted
04 Sep 2015
Accepted
05 Oct 2015
First published
05 Oct 2015

Chem. Commun., 2015,51, 17241-17244

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Liquid marbles as a micro-reactor for efficient radical alternating copolymerization of diene monomer and oxygen

E. Sato, M. Yuri, S. Fujii, T. Nishiyama, Y. Nakamura and H. Horibe, Chem. Commun., 2015, 51, 17241 DOI: 10.1039/C5CC07421E

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