I2-induced SC–SC transformation within two-dimensional Zn(II)-triazole framework: an ideal detector of cyano-containing molecules

Ying Wang; Jin-Min Yi; Meng-Yuan Zhang; Ping Xu; Xiao-Jun Zhao

doi:10.1039/C5CC09279E

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I₂-induced SC–SC transformation within two-dimensional Zn(ii)-triazole framework: an ideal detector of cyano-containing molecules†

Ying Wang,*^ab Jin-Min Yi,^a Meng-Yuan Zhang,^a Ping Xu^a and Xiao-Jun Zhao*^a

Author affiliations

* Corresponding authors

^a Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China
E-mail: wangying790601@163.com

^b Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Abstract

A novel interpenetrated 2D + 2D → 2D architechture {[Zn(BTPS)(TPA)]·1.5DMF·H₂O}_n (1) has been constructed under solvothermal conditions. Interestingly, I₂-induced single-crystal-to-single-crystal transformation to {[Zn(BTPS)(I)(TPA)_1.5]·1.5H₂O}_n (1′) showed a 2D + 1D → 2D array. Luminescent properties indicated that 1 represents the first example of selective recognition toward cyano-containing molecules.

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Article information

DOI: https://doi.org/10.1039/C5CC09279E
Article type: Communication
Submitted: 09 Nov 2015
Accepted: 16 Dec 2015
First published: 16 Dec 2015

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Chem. Commun., 2016,52, 3099-3102

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I₂-induced SC–SC transformation within two-dimensional Zn(II)-triazole framework: an ideal detector of cyano-containing molecules

Y. Wang, J. Yi, M. Zhang, P. Xu and X. Zhao, Chem. Commun., 2016, 52, 3099 DOI: 10.1039/C5CC09279E

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