Issue 13, 2016

Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

Abstract

Ionic transport (for applications in nanofluidics or membranes) and “ionic diode” phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn2+ and 2-methylimidazole as an “asymmetric plug” into a 20 μm diameter pore in a ca. 6 μm thin poly-ethylene-terephthalate (PET) film.

Graphical abstract: Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

Supplementary files

Article information

Article type
Communication
Submitted
26 Nov 2015
Accepted
11 Jan 2016
First published
11 Jan 2016

Chem. Commun., 2016,52, 2792-2794

Author version available

Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena

E. Madrid, M. A. Buckingham, J. M. Stone, A. T. Rogers, W. J. Gee, A. D. Burrows, P. R. Raithby, V. Celorrio, D. J. Fermin and F. Marken, Chem. Commun., 2016, 52, 2792 DOI: 10.1039/C5CC09780K

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