Issue 12, 2016
From the journal:

Chemical Communications

Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow†

Quentin Lefebvre,*a   Norbert Hoffmann*b  and  Magnus Rueping*a  

* Corresponding authors

a Institute of Organic Chemistry, RWTH Aachen, Landoltweg 1, Aachen, Germany
E-mail: Magnus.Rueping@rwth-aachen.de, quentin.lefebvre@ens-lyon.org

b CNRS, Université de Reims Champagne-Ardenne Institut de Chimie Moléculaire de Reims (UMR 6229), Equipe de Photochimie, UFR Sciences, 51687 Reims, France
E-mail: norbert.hoffmann@univ-reims.fr

Abstract

Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.

Graphical abstract: Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

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Article information

DOI
https://doi.org/10.1039/C5CC09881E
Article type
Communication
Submitted
30 Nov 2015
Accepted
24 Dec 2015
First published
06 Jan 2016

Chem. Commun., 2016,52, 2493-2496

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Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Q. Lefebvre, N. Hoffmann and M. Rueping, Chem. Commun., 2016, 52, 2493 DOI: 10.1039/C5CC09881E

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