Issue 13, 2016

An azine-linked hexaphenylbenzene based covalent organic framework

Abstract

In this communication, we report an azine linked covalent organic framework based on a six-fold symmetric hexphenylbenzene (HEX) monomer functionalized with aldehyde groups. HEX-COF 1 has an average pore size of 1 nm, a surface area in excess of 1200 m2 g−1 and shows excellent sorption capability for carbon dioxide (20 wt%) and methane (2.3 wt%) at 273 K and 1 atm.

Graphical abstract: An azine-linked hexaphenylbenzene based covalent organic framework

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2015
Accepted
10 Jan 2016
First published
11 Jan 2016

Chem. Commun., 2016,52, 2843-2845

An azine-linked hexaphenylbenzene based covalent organic framework

S. B. Alahakoon, C. M. Thompson, A. X. Nguyen, G. Occhialini, G. T. McCandless and R. A. Smaldone, Chem. Commun., 2016, 52, 2843 DOI: 10.1039/C5CC10408D

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