A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure

D. García; L. Rodríguez-Pérez; M. A. Herranz; D. Peña; E. Guitián; S. Bailey; Q. Al-Galiby; M. Noori; C. J. Lambert; D. Pérez; N. Martín

doi:10.1039/C5CC10462A

A C₆₀-aryne building block: synthesis of a hybrid all-carbon nanostructure†‡

D. García,^a L. Rodríguez-Pérez,^b M. A. Herranz,^b D. Peña,^a E. Guitián,^a S. Bailey,^c Q. Al-Galiby,^cd M. Noori,^c C. J. Lambert,

^c D. Pérez*^a and N. Martín*^be

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* Corresponding authors

^a Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela 15782, Spain
E-mail: dolores.perez@usc.es

^b Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid, Spain
E-mail: nazmar@ucm.es

^c Physics Department, Lancaster University, LA1 4YB Lancaster, UK

^d Physics Department, College of Education, Al-Qadisiyah University, IRAQ

^e IMDEA-Nanociencia, c/Faraday 9, Campus Cantoblanco, 28049 Madrid, Spain

Abstract

The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.

Chemical Communications

A C₆₀-aryne building block: synthesis of a hybrid all-carbon nanostructure†‡

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A C₆₀-aryne building block: synthesis of a hybrid all-carbon nanostructure

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