An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups

Keke Wang; Hongliang Huang; Wenjuan Xue; Dahuan Liu; Xudong Zhao; Yuanlong Xiao; Zhengjie Li; Qingyuan Yang; Luyan Wang; Chongli Zhong

doi:10.1039/C5CE00269A

An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups†

Keke Wang,‡^a Hongliang Huang,‡^a Wenjuan Xue,^a Dahuan Liu,*^a Xudong Zhao,^a Yuanlong Xiao,^a Zhengjie Li,^a Qingyuan Yang,^a Luyan Wang*^b and Chongli Zhong^a

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^a State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
E-mail: liudh@mail.buct.edu.cn

^b North College, Beijing University of Chemical Technology, Beijing 065201, China
E-mail: xgz_good2006@126.com

Abstract

An ultrastable metal–organic framework can remain intact in pH = 0 to 12 solutions and boiling water, attributed to the steric hindrance and electronic effect of methyl groups as well as strong Zr–O bonds. This MOF exhibits good adsorption and sensing performance for Hg⁰ vapor because of the presence of thiophene.

CrystEngComm

An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups†

Abstract

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An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups

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