Issue 35, 2015
From the journal:

Physical Chemistry Chemical Physics

Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures†

Marco Giorgetti,*a   Giuliana Aquilanti,b   Michela Ciaboccoc  and  Mario Berrettoni ORCID logo c  

* Corresponding authors

a Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Viale Risorgimento 4, 40136 Bologna, Italy
E-mail: marco.giorgetti@unibo.it
Fax: +39 0512093690
Tel: +39 0512093666

b Elettra – Sincrotrone Trieste S.C.p.A., s.s. 14 km 163.5, 34149 Basovizza, Trieste, Italy

c Dipartimento di Chimica Industriale “Toso Montanari”, UOS, Campus di Rimini, Università di Bologna, Via dei Mille 39, 47921 Rimini, Italy

Abstract

A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by high-resolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shell.

Graphical abstract: Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures

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Article information

DOI
https://doi.org/10.1039/C5CP03580E
Article type
Communication
Submitted
21 Jun 2015
Accepted
26 Jul 2015
First published
28 Jul 2015

Phys. Chem. Chem. Phys., 2015,17, 22519-22522

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Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures

M. Giorgetti, G. Aquilanti, M. Ciabocco and M. Berrettoni, Phys. Chem. Chem. Phys., 2015, 17, 22519 DOI: 10.1039/C5CP03580E

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