Issue 14, 2015

A CH2Cl2 complex of a [Rh(pincer)]+ cation

Abstract

The CH2Cl2 complex [Rh(tBuPONOP)(κ1-ClCH2Cl)][BArF4] is reported, that also acts as a useful synthon for other complexes such as N2, CO and H2 adducts; while the analogous PNP complex undergoes C–Cl activation.

Graphical abstract: A CH2Cl2 complex of a [Rh(pincer)]+ cation

Supplementary files

Article information

Article type
Communication
Submitted
02 Feb 2015
Accepted
05 Mar 2015
First published
05 Mar 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 6340-6342

A CH2Cl2 complex of a [Rh(pincer)]+ cation

G. M. Adams, F. M. Chadwick, S. D. Pike and A. S. Weller, Dalton Trans., 2015, 44, 6340 DOI: 10.1039/C5DT00481K

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