Issue 34, 2015
From the journal:

Dalton Transactions

Two phosphaalkene radical cations with inverse spin density distributions†

Xiaobo Pan,‡a   Xingyong Wang,‡*a   Zaichao Zhangb  and  Xinping Wang*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
E-mail: wangxingyong@nju.edu.cn, xpwang@nju.edu.cn

b School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an 223300, China

Abstract

Two phosphaalkene radical cations 1˙+ and 2˙+ have been reported. 1˙+ is stable in the solid state and has been structurally characterized. 2˙+ only remains persistent in solution. 1˙+ is described as a phosphorus-centered radical, while 2˙+ as a delocalized radical with little contribution from phosphorus.

Graphical abstract: Two phosphaalkene radical cations with inverse spin density distributions

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Article information

DOI
https://doi.org/10.1039/C5DT00656B
Article type
Communication
Submitted
13 Feb 2015
Accepted
24 Mar 2015
First published
24 Mar 2015

Dalton Trans., 2015,44, 15099-15102

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Two phosphaalkene radical cations with inverse spin density distributions

X. Pan, X. Wang, Z. Zhang and X. Wang, Dalton Trans., 2015, 44, 15099 DOI: 10.1039/C5DT00656B

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