A multi-component polyoxometalate and its catalytic performance for CO2 cycloaddition reactions

Shumin Chen; Ying Liu; Jipeng Guo; Pengzhen Li; Zhiyuan Huo; Pengtao Ma; Jingyang Niu; Jingping Wang

doi:10.1039/C5DT01046B

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A multi-component polyoxometalate and its catalytic performance for CO₂ cycloaddition reactions†

Shumin Chen,^a Ying Liu,^a Jipeng Guo,^a Pengzhen Li,^a Zhiyuan Huo,^a Pengtao Ma,^a Jingyang Niu*^a and Jingping Wang*^a

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* Corresponding authors

^a Key Laboratory of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: (+86) 371-23886876

Abstract

A multi-component polyoxometalate based on earth-abundant elements (NH₄)₁₀[Co₈(H₂O)₁₀V₁₀Mo₂₃O₁₀₄(OH)₆]·34.5H₂O (1) has been successfully obtained and characterized. Furthermore, compound 1 acted as a Lewis acid catalyst and promoted the conversion of carbon dioxide to a cyclic carbonate under mild reaction conditions.

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Article information

DOI: https://doi.org/10.1039/C5DT01046B
Article type: Communication
Submitted: 16 Mar 2015
Accepted: 01 May 2015
First published: 07 May 2015

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Dalton Trans., 2015,44, 10152-10155

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A multi-component polyoxometalate and its catalytic performance for CO₂ cycloaddition reactions

S. Chen, Y. Liu, J. Guo, P. Li, Z. Huo, P. Ma, J. Niu and J. Wang, Dalton Trans., 2015, 44, 10152 DOI: 10.1039/C5DT01046B

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Dalton Transactions