Benzimidazole-functionalized ancillary ligands for heteroleptic Ru(ii) complexes: synthesis, characterization and dye-sensitized solar cell applications†
Abstract
We have designed and synthesized heteroleptic Ru(II) complexes with a pyridine-benzimidazole ligand (PYBI) for dye-sensitized solar cell (DSSC) applications. The PYBI ligand has major advantages by having the flexibility to introduce appropriate substituents at the four readily available positions through molecular engineering (