Issue 43, 2015
From the journal:

Dalton Transactions

Water stable triazolyl phosphonate MOFs: steep water uptake and facile regeneration†

S. Begum,ab   S. Horike,b   S. Kitagawa*bc  and  H. Krautscheid*a  

* Corresponding authors

a Fakultät für Chemie und Mineralogie, Universität Leipzig, Johannisallee 29, Leipzig 04103, Germany
E-mail: krautscheid@rz.uni-leipzig.de
Fax: +0049-3419736199
Tel: +0049-3419736172

b Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kitagawa@icems.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

c Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

The new microporous cobalt triazolyl phosphonate MOF 3α[Co4L3(μ3-OH)(H2O)3](SO4)0.5·xH2O (L2− = 4-(4H-1,2,4-triazol-4-yl)-phenyl phosphonate) exhibits exciting features including high water stability, reversible hydration–dehydration, steep water uptake in repeated cycles at low water vapor pressures and reactivation at room temperature under mild evacuation.

Graphical abstract: Water stable triazolyl phosphonate MOFs: steep water uptake and facile regeneration

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Article information

DOI
https://doi.org/10.1039/C5DT02651B
Article type
Communication
Submitted
13 Jul 2015
Accepted
01 Oct 2015
First published
05 Oct 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 18727-18730

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Water stable triazolyl phosphonate MOFs: steep water uptake and facile regeneration

S. Begum, S. Horike, S. Kitagawa and H. Krautscheid, Dalton Trans., 2015, 44, 18727 DOI: 10.1039/C5DT02651B

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