B(C6F5)3-catalyzed metal-free hydrogenation of 3,6-diarylpyridazines

Wei Wang; Wei Meng; Haifeng Du

doi:10.1039/C5DT03872C

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B(C₆F₅)₃-catalyzed metal-free hydrogenation of 3,6-diarylpyridazines†

Wei Wang,^a Wei Meng^a and Haifeng Du*^a

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* Corresponding authors

^a Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: haifengdu@iccas.ac.cn
Fax: +86-10-62554449
Tel: +86-10-62652117

Abstract

This paper describes the first metal-free hydrogenation of 3,6-diarylpyridazines, which was successfully realized using B(C₆F₅)₃ as a catalyst. A variety of 1,4,5,6-tetrahydropyridazine derivatives were furnished in 85–95% yields.

This article is part of the themed collection: Main Group Transformations

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Article information

DOI: https://doi.org/10.1039/C5DT03872C
Article type: Communication
Submitted: 04 Oct 2015
Accepted: 01 Dec 2015
First published: 03 Dec 2015

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Dalton Trans., 2016,45, 5945-5948

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B(C₆F₅)₃-catalyzed metal-free hydrogenation of 3,6-diarylpyridazines

W. Wang, W. Meng and H. Du, Dalton Trans., 2016, 45, 5945 DOI: 10.1039/C5DT03872C

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Dalton Transactions