Planar Dy3 + Dy3 clusters: design, structure and axial ligand perturbed magnetic dynamics

Xiao-Lei Li; Han Li; Di-Ming Chen; Chao Wang; Jianfeng Wu; Jinkui Tang; Wei Shi; Peng Cheng

doi:10.1039/C5DT03931B

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Planar Dy₃ + Dy₃ clusters: design, structure and axial ligand perturbed magnetic dynamics†

Xiao-Lei Li,^ab Han Li,^a Di-Ming Chen,^a Chao Wang,^b Jianfeng Wu,^b Jinkui Tang,*^b Wei Shi*^a and Peng Cheng*^a

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* Corresponding authors

^a Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China

^b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
E-mail: tang@ciac.ac.cn
Fax: +86 431 85262878

Abstract

Two unique Dy₆ complexes with fascinating Dy₃ + Dy₃ structures were assembled, showing single-molecule magnetic behavior with high energy barriers of 116 and 181 K for Dy₆–NO₃ and Dy₆–SCN.

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Article information

DOI: https://doi.org/10.1039/C5DT03931B
Article type: Communication
Submitted: 08 Oct 2015
Accepted: 20 Oct 2015
First published: 09 Nov 2015

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Dalton Trans., 2015,44, 20316-20320

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Planar Dy₃ + Dy₃ clusters: design, structure and axial ligand perturbed magnetic dynamics

X. Li, H. Li, D. Chen, C. Wang, J. Wu, J. Tang, W. Shi and P. Cheng, Dalton Trans., 2015, 44, 20316 DOI: 10.1039/C5DT03931B

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