Issue 3, 2016

Surprising coordination for low-valent actinides resembling uranyl(vi) in thorium(iv) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

Abstract

Three thorium(IV)-based metal–organic hybrid compounds with 2D layered and 3D framework structures exhibiting graphene-like (6,3) sheet topologies were prepared with linkers with threefold symmetry. These compounds contain rare and relatively anisotropic coordination environments for low-valent actinides that are similar to those often observed for high-valent actinide ions.

Graphical abstract: Surprising coordination for low-valent actinides resembling uranyl(vi) in thorium(iv) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

Supplementary files

Article information

Article type
Communication
Submitted
24 Oct 2015
Accepted
04 Dec 2015
First published
07 Dec 2015

Dalton Trans., 2016,45, 918-921

Author version available

Surprising coordination for low-valent actinides resembling uranyl(VI) in thorium(IV) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

Y. Li, Z. Weng, Y. Wang, L. Chen, D. Sheng, J. Diwu, Z. Chai, T. E. Albrecht-Schmitt and S. Wang, Dalton Trans., 2016, 45, 918 DOI: 10.1039/C5DT04183J

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