Issue 7, 2016
From the journal:

Dalton Transactions

A functional mesoporous ionic crystal based on polyoxometalate†

Ryosuke Kawahara,a   Kazuma Niinomi,a   Junko N. Kondo,bc   Mitsuhiro Hibino,d   Noritaka Mizunod  and  Sayaka Uchida*ab  

* Corresponding authors

a Department of Basic Science, School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan
E-mail: csayaka@mail.ecc.u-tokyo.ac.jp

b JST-PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

c Chemical Resources Laboratory, Tokyo Institute of Technology, 4259-R1-10 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

d Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

A mesoporous ionic crystal is synthesized with a polyoxometalate and a macrocation with polar cyano groups. The compound possesses one-dimensional mesopores with an opening of 3.0 × 2.0 nm. The compound shows high proton conductivity and catalytic activity, which are due to the water molecules in the mesopores.

Graphical abstract: A functional mesoporous ionic crystal based on polyoxometalate

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Article information

DOI
https://doi.org/10.1039/C5DT04556H
Article type
Communication
Submitted
20 Nov 2015
Accepted
15 Jan 2016
First published
15 Jan 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 2805-2809

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A functional mesoporous ionic crystal based on polyoxometalate

R. Kawahara, K. Niinomi, J. N. Kondo, M. Hibino, N. Mizuno and S. Uchida, Dalton Trans., 2016, 45, 2805 DOI: 10.1039/C5DT04556H

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