Issue 13, 2016
From the journal:

Dalton Transactions

Photocatalytic hydrogen evolution by Cu(ii) complexes†

Junfei Wang,ab   Chao Li,a   Qianxiong Zhou,a   Weibo Wang,a   Yuanjun Hou,*a   Baowen Zhanga  and  Xuesong Wang*a  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: xswang@mail.ipc.ac.cn, yuanjunhou@yahoo.com

b Graduate School of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

[Cu(TMPA)Cl]Cl (1) and [Cu(Cl-TMPA)Cl2] (2) exhibited efficient photocatalytic H2 evolution with a TON of 6108 and 10014 (6 h), respectively, in CH3CN/H2O solution (9 : 1, v/v) containing an Ir complex as the photosensitizer and triethylamine as the sacrificial reductant, representing the first example of photocatalytic Cu complex-based water reduction catalysts.

Graphical abstract: Photocatalytic hydrogen evolution by Cu(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C5DT04628A
Article type
Communication
Submitted
26 Nov 2015
Accepted
02 Mar 2016
First published
02 Mar 2016

Dalton Trans., 2016,45, 5439-5443

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Photocatalytic hydrogen evolution by Cu(II) complexes

J. Wang, C. Li, Q. Zhou, W. Wang, Y. Hou, B. Zhang and X. Wang, Dalton Trans., 2016, 45, 5439 DOI: 10.1039/C5DT04628A

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