Synthesis and characterization of [(HPO3)6Mo21O60(H2O)4]8−: a new redox active heteropoly blue cluster with layered shape containing a phosphite template that self-assembles under controlled microwave irradiation

Xiang-xiao Jin; Wei-dong Yu; Yan-Mei Nie; Meng-Shu Liu; Jun Yan

doi:10.1039/C5DT04977F

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Synthesis and characterization of [(HPO₃)₆Mo₂₁O₆₀(H₂O)₄]⁸⁻: a new redox active heteropoly blue cluster with layered shape containing a phosphite template that self-assembles under controlled microwave irradiation†

Xiang-xiao Jin,^a Wei-dong Yu,^a Yan-Mei Nie,^a Meng-Shu Liu^a and Jun Yan*^a

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China
E-mail: yanjun@csu.edu.cn

Abstract

The microwave-driven synthesis of a heteropoly blue cluster yields a redox active cluster, [(HPO₃)₆Mo₂₁O₆₀(H₂O)₄]⁸⁻, templated by six phosphite anions whereby two phosphites template a tri-lucunary {Mo₁₅} Dawson structure, and one templates a {Mo₆} ring with two of the three remaining phosphites acting as bridging ligands connecting the ring to the {Mo₁₅}.

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Article information

DOI: https://doi.org/10.1039/C5DT04977F
Article type: Communication
Submitted: 23 Dec 2015
Accepted: 26 Jan 2016
First published: 26 Jan 2016

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Dalton Trans., 2016,45, 3268-3271

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Synthesis and characterization of [(HPO₃)₆Mo₂₁O₆₀(H₂O)₄]⁸⁻: a new redox active heteropoly blue cluster with layered shape containing a phosphite template that self-assembles under controlled microwave irradiation

X. Jin, W. Yu, Y. Nie, M. Liu and J. Yan, Dalton Trans., 2016, 45, 3268 DOI: 10.1039/C5DT04977F

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Dalton Transactions