Issue 4, 2016

Base-free conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over a Ru/C catalyst

Abstract

The catalytic conversion of 5-hydroxymethyl furfural (HMF) to 2,5-furandicarboxylic acid (FDCA) over a commercial Ru/C catalyst in a base-free aqueous solution was studied with 88% FDCA yield. A self-catalyzed system using FDCA for the dehydration of fructose to HMF followed by base-free conversion of HMF to FDCA was also demonstrated with 53% overall yield.

Graphical abstract: Base-free conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over a Ru/C catalyst

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2015
Accepted
05 Oct 2015
First published
06 Oct 2015

Green Chem., 2016,18, 979-983

Base-free conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over a Ru/C catalyst

G. Yi, S. P. Teong and Y. Zhang, Green Chem., 2016, 18, 979 DOI: 10.1039/C5GC01584G

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