Issue 7, 2015

Isolable arene sandwiched copper(i) pyrazolates

Abstract

The π-acid/π-base adducts of {[3,5-(CF3)2Pz]Cu}3[Cu3] and benzene [Bz], mesitylene [Mes] and naphthalene [Nap] have been isolated. They form columnar structures of the type {[Bz][Cu3]2}, {[Mes][Cu3]} and {[Nap][Cu3]} in the solid state, and are luminescent.

Graphical abstract: Isolable arene sandwiched copper(i) pyrazolates

Supplementary files

Article information

Article type
Letter
Submitted
22 Apr 2015
Accepted
11 May 2015
First published
12 May 2015

New J. Chem., 2015,39, 5092-5095

Author version available

Isolable arene sandwiched copper(I) pyrazolates

N. B. Jayaratna, C. V. Hettiarachchi, M. Yousufuddin and H. V. Rasika Dias, New J. Chem., 2015, 39, 5092 DOI: 10.1039/C5NJ01002K

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