Issue 12, 2015

Selective stepwise oxidation of 1,4-decamethoxypillar[5]arene

Abstract

For the first time, the 1H and 13C{1H} NMR data were classified and analyzed for the pillar[5]arenes with one, two, three and five 1,4-benzoquinone fragments obtained in good yields. The empirical relationships established make it possible to define the relative position of the quinone and aryl fragments to each other in the oxidation products of any pillar[n]arenes.

Graphical abstract: Selective stepwise oxidation of 1,4-decamethoxypillar[5]arene

Supplementary files

Article information

Article type
Paper
Submitted
24 Jul 2015
Accepted
09 Sep 2015
First published
11 Sep 2015

New J. Chem., 2015,39, 9215-9220

Selective stepwise oxidation of 1,4-decamethoxypillar[5]arene

D. N. Shurpik, P. L. Padnya, L. I. Makhmutova, L. S. Yakimova and I. I. Stoikov, New J. Chem., 2015, 39, 9215 DOI: 10.1039/C5NJ01951F

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