Issue 4, 2016
From the journal:

New Journal of Chemistry

A simple protocol for Cu-catalyzed protodecarboxylation of (hetero)aromatic carboxylic acids†

Zhaojie Li,a   Zhengjiang Fu,*ab   Haixia Zhang,‡a   Jiao Long,‡a   Yuanyuan Songa  and  Hu Cai*a  

* Corresponding authors

a College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China
E-mail: fuzhengjiang@ncu.edu.cn, caihu@ncu.edu.cn

b State Key Laboratory of Structural Chemistry, Fuzhou, Fujian 350002, China

Abstract

A simple and practical protodecarboxylation of o-nitrobenzoic acids as well as heteroaromatic carboxylic acids with various substituents via using CuI/Et3N has been established. This transformation provides a viable and low-cost approach to generating previously unavailable substituted arenes from readily accessible aryl carboxylic acids as the starting materials.

Graphical abstract: A simple protocol for Cu-catalyzed protodecarboxylation of (hetero)aromatic carboxylic acids

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Article information

DOI
https://doi.org/10.1039/C5NJ02792F
Article type
Letter
Submitted
10 Oct 2015
Accepted
02 Feb 2016
First published
03 Feb 2016

New J. Chem., 2016,40, 3014-3018

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A simple protocol for Cu-catalyzed protodecarboxylation of (hetero)aromatic carboxylic acids

Z. Li, Z. Fu, H. Zhang, J. Long, Y. Song and H. Cai, New J. Chem., 2016, 40, 3014 DOI: 10.1039/C5NJ02792F

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