Issue 10, 2015
From the journal:

Organic & Biomolecular Chemistry

Rhodium-catalyzed hydroarylation of alkynes via tetrazole-directed C–H activation†

Bin Chen,a   Yan Jiang,a   Jiang Chenga  and  Jin-Tao Yu*a  

* Corresponding authors

a School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, Changzhou 213164, P. R. China
E-mail: yujintao@cczu.edu.cn

Abstract

A rhodium-catalyzed hydroarylation of alkynes with aryl tetrazoles through tetrazole-directed C–H activation was developed. This procedure has broad substrate scopes, and a variety of mono- and dialkenylated products were regioselectively obtained in moderate to excellent yields.

Graphical abstract: Rhodium-catalyzed hydroarylation of alkynes via tetrazole-directed C–H activation

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Article information

DOI
https://doi.org/10.1039/C5OB00064E
Article type
Communication
Submitted
14 Jan 2015
Accepted
28 Jan 2015
First published
28 Jan 2015

Org. Biomol. Chem., 2015,13, 2901-2904

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Rhodium-catalyzed hydroarylation of alkynes via tetrazole-directed C–H activation

B. Chen, Y. Jiang, J. Cheng and J. Yu, Org. Biomol. Chem., 2015, 13, 2901 DOI: 10.1039/C5OB00064E

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