Issue 3, 2016

Iodine-catalyzed thiolation of electron-rich aromatics using sulfonyl hydrazides as sulfenylation reagents

Abstract

Iodine-catalyzed thiolation of electron-rich aromatics, including substituted anisole, thioanisole, phenol, toluene, and naphthalene, using sulfonyl hydrazides as sulfenylation reagents was carried out. Sulfonothioates, the products of decomposition of sulfonyl hydrazides in the presence of iodine, are proposed as the major sulfenylation species in this transformation.

Graphical abstract: Iodine-catalyzed thiolation of electron-rich aromatics using sulfonyl hydrazides as sulfenylation reagents

Supplementary files

Article information

Article type
Paper
Submitted
23 Oct 2015
Accepted
19 Nov 2015
First published
19 Nov 2015

Org. Biomol. Chem., 2016,14, 1131-1137

Author version available

Iodine-catalyzed thiolation of electron-rich aromatics using sulfonyl hydrazides as sulfenylation reagents

X. Zhao, T. Li, L. Zhang and K. Lu, Org. Biomol. Chem., 2016, 14, 1131 DOI: 10.1039/C5OB02193F

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