Issue 8, 2015

Autoinductive thiolation/oxygenation of alkenes at room temperature

Abstract

A new reaction for O2 fixation is rationally demonstrated, in which radical thiolation/oxygenation of activated alkenes proceeds spontaneously at room temperature with no need for any additives. EPR and operando IR experiments revealed that O2 serves as the initiator to trigger this radical reaction and that autoinductive processes are the critical factor to drive the reaction.

Graphical abstract: Autoinductive thiolation/oxygenation of alkenes at room temperature

Supplementary files

Article information

Article type
Research Article
Submitted
29 Mar 2015
Accepted
07 May 2015
First published
07 May 2015

Org. Chem. Front., 2015,2, 908-912

Autoinductive thiolation/oxygenation of alkenes at room temperature

Q. Lu, H. Wang, P. Peng, C. Liu, Z. Huang, Y. Luo and A. Lei, Org. Chem. Front., 2015, 2, 908 DOI: 10.1039/C5QO00102A

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