Issue 41, 2015

Easily deconstructed, high aspect ratio cellulose nanofibres from Triodia pungens; an abundant grass of Australia's arid zone

Abstract

The production of high aspect ratio cellulose nanofibres without resorting to very harsh mechanical and/or chemical processing steps remains a challenge that hinders progress in the fast-moving nanocellulose field. In response to this challenge, herein we report the preparation of high aspect ratio (>500) and small diameter (<8 nm) cellulose nanofibrils through the deconstruction of Australian native ‘spinifex’ grass (Triodia pungens) by applying very mild pulping conditions combined with only one pass of high pressure homogenization. Spinifex grass has an unusually high hemicellulose content, which facilitates this easy fibrillation process. Tensile measurements of the nanopaper produced by vacuum filtration indicated a high toughness of about 12 MJ m−3, a tensile strength of 82 MPa and a high elongation at break of 18%. The transverse elastic modulus of single nanofibrils analysed by AM-FM is in the range of 19–24 GPa. Under these mild processing conditions, Triodia pungens nanofibrils retained their crystallinity.

Graphical abstract: Easily deconstructed, high aspect ratio cellulose nanofibres from Triodia pungens; an abundant grass of Australia's arid zone

Supplementary files

Article information

Article type
Paper
Submitted
15 Feb 2015
Accepted
26 Mar 2015
First published
26 Mar 2015

RSC Adv., 2015,5, 32124-32132

Author version available

Easily deconstructed, high aspect ratio cellulose nanofibres from Triodia pungens; an abundant grass of Australia's arid zone

N. Amiralian, P. K. Annamalai, P. Memmott, E. Taran, S. Schmidt and D. J. Martin, RSC Adv., 2015, 5, 32124 DOI: 10.1039/C5RA02936H

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