Issue 43, 2015
From the journal:

RSC Advances

Synthesis of monofluoroalkenes through selective hydrodefluorination of gem-difluoroalkenes with Red-Al®†

Jingjing Wu,*ac   Juan Xiao,b   Wenpeng Daib  and  Song Cao*bc  

* Corresponding authors

a School of Chemical and Environmental Engineering, Shanghai Institute of Technology (SIT), Shanghai 201418, China
E-mail: wujj@sit.edu.cn
Fax: +86-21-60877231
Tel: +86-21-60877220

b Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology (ECUST), Shanghai 200237, China
E-mail: scao@ecust.edu.cn

c Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry (SIOC), Chinese Academy of Sciences, Shanghai 200032, China

Abstract

A novel and practical approach for the selective hydrodefluorination of gem-difluoroalkenes using Red-Al® as a reductant at room temperature in CH2Cl2 without any additional base and metal catalyst was reported. Various monofluoroalkenes were obtained in moderate to high yields with good E-selectivity.

Graphical abstract: Synthesis of monofluoroalkenes through selective hydrodefluorination of gem-difluoroalkenes with Red-Al®

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Article information

DOI
https://doi.org/10.1039/C5RA04221F
Article type
Communication
Submitted
10 Mar 2015
Accepted
08 Apr 2015
First published
08 Apr 2015

RSC Adv., 2015,5, 34498-34501

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Synthesis of monofluoroalkenes through selective hydrodefluorination of gem-difluoroalkenes with Red-Al®

J. Wu, J. Xiao, W. Dai and S. Cao, RSC Adv., 2015, 5, 34498 DOI: 10.1039/C5RA04221F

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