Palladium-catalyzed Heck coupling of arylhydrazines via C–NHNH2 bond activation

Jin-Biao Liu; Fu-Jiao Chen; Na Liu; Jiang Hu

doi:10.1039/C5RA05131B

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Palladium-catalyzed Heck coupling of arylhydrazines via C–NHNH₂ bond activation†

Jin-Biao Liu,*^ab Fu-Jiao Chen,^a Na Liu^a and Jiang Hu^a

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* Corresponding authors

^a School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China
E-mail: liujbgood@hotmail.com

^b Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University, Nanchang 330022, China

Abstract

A novel palladium-catalyzed Heck coupling reaction of arylhydrazines with olefins is described, which affords various styrenes with high efficiency. This transformation proceeds through a C–NHNH₂ bond activation under mild conditions.

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Article information

DOI: https://doi.org/10.1039/C5RA05131B
Article type: Communication
Submitted: 23 Mar 2015
Accepted: 07 May 2015
First published: 07 May 2015

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RSC Adv., 2015,5, 45843-45846

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Palladium-catalyzed Heck coupling of arylhydrazines via C–NHNH₂ bond activation

J. Liu, F. Chen, N. Liu and J. Hu, RSC Adv., 2015, 5, 45843 DOI: 10.1039/C5RA05131B

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