The first study of surface modified silica nanoparticles in pressure-decreasing application

Abstract

In this study, hydrophobic silica nanoparticles were prepared by the surface modification of silica nanoparticles using dimethyldichlorosilane. Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy were employed for the characterization of the raw silica nanoparticles and modified silica nanoparticles. The results showed that methyl groups are successfully grafted on the surface of silica nanoparticles. The titration method was employed to quantitatively determine the surface hydroxyl number of silica nanoparticles; the result demonstrated that the surface hydroxyl number of silica nanoparticles significantly decreases after modification. The modified silica nanoparticles was dispersed in water using TX-100 as the dispersant and NaOH to adjust the pH. The dispersion was injected into an oil-treated artificial core, the injecting pressure of the NaCl solution (5 wt%) before and after injection was measured. The result showed that the hydrophobic silica nanoparticles exhibit a good pressure-decreasing ability. The contact angle of the slabbed core was measured, the contact angle increased from 36° to 134° after it was treated by the modified silica nanoparticle dispersion. Transmission electron microscopy was employed for the characterization of the modified silica nanoparticles. Scanning electron microscopy was employed for the characterization of the treated core; the result showed that the modified silica nanoparticles are adsorbed on the surface of the core and forms a hydrophobic layer, changing the wettability of the sand surface from water wet to oil wet, thereby decreasing the flowing pressure.