The first ligand-free ferrous chloride catalyzed anti-Markovnikov hydroboration of un-activated aryl alkenes with bis(pinacolato)diboron (B2pin2) has been reported. The reactions proceeded smoothly with high regioselectivity for a large range of aryl alkenes with wide functional-group compatibility and low catalyst loading under mild conditions.
Y. Liu, Y. Zhou, H. Wang and J. Qu, RSC Adv., 2015, 5, 73705 DOI: 10.1039/C5RA14869C
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