Issue 88, 2015
From the journal:

RSC Advances

Chloroform-based Atherton–Todd-type reactions of alcohols and thiols with secondary phosphine oxides generating phosphinothioates and phosphinates†

Shan Li,a   Tieqiao Chen,*a   Yuta Sagab  and  Li-Biao Han*c  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
E-mail: chentieqiao@hnu.edu.cn

b Katayama Chemical Industries Co., Ltd, 26-22, 3-Chome, Higasinaniwa-cho, Amagasaki, Hyogo 660-0892, Japan

c National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan
E-mail: libiao-han@aist.go.jp

Abstract

Chloroform-based Atherton–Todd-type reactions of alcohols and thiols with secondary phosphine oxides, generating phosphinothioates and phosphinates, respectively, are described. Various valuable phosphinothioates and phosphinates including those with functional groups are readily prepared under mild reaction conditions.

Graphical abstract: Chloroform-based Atherton–Todd-type reactions of alcohols and thiols with secondary phosphine oxides generating phosphinothioates and phosphinates

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Article information

DOI
https://doi.org/10.1039/C5RA16015D
Article type
Communication
Submitted
10 Aug 2015
Accepted
17 Aug 2015
First published
17 Aug 2015

RSC Adv., 2015,5, 71544-71546

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Chloroform-based Atherton–Todd-type reactions of alcohols and thiols with secondary phosphine oxides generating phosphinothioates and phosphinates

S. Li, T. Chen, Y. Saga and L. Han, RSC Adv., 2015, 5, 71544 DOI: 10.1039/C5RA16015D

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