Effect of promoters on the HDS activity of alumina-supported Co–Mo sulfide catalysts

Abstract

A series of CoMo/δ-Al₂O₃ catalysts promoted by different organic and inorganic cobalt salts were successfully prepared using low-cost δ-Al₂O₃ as a support through a two-step incipient-wetness impregnation method. The obtained catalysts were indicated as MoCo-N/δ, MoCo-S/δ, MoCo-A/δ and MoCo-D/δ, in which N, S, A, D, and δ represent cobalt nitrate, cobalt sulfate, cobalt acetate, cobalt diacetylmethane, and δ-Al₂O₃, respectively. The as-synthesized catalysts were introduced to the hydrodesulfurization (HDS) process of fluid catalytic cracking (FCC) diesel, in a fixed-bed reactor. The oxidized catalysts and the corresponding sulfurized catalysts for HDS were characterized by UV-vis, Raman, X-ray diffraction, TPR, and XPS techniques. The catalytic activities followed the order of MoCo-A/δ < MoCo-N/δ < MoCo-D/δ < MoCo-S/δ. These catalytic results could be ascribed to the introduction of different cobalt salts decreasing the metal-support interaction (MSI), and led to the formation of easily reduced Mo species, which were the precursors to form more active sites that could enhance the HDS activity of the catalysts. The highest activity shown by the MoCo-S/δ catalyst could be ascribed to its (1) higher metal dispersion, (2) lower Mo reduction temperature, and (3) higher sulfurization degree. As a result, the excellent catalytic performance could be attributed to its outstanding promoter effect.