Issue 130, 2015
From the journal:

RSC Advances

Iodine-mediated thiolation of phenol/phenylamine derivatives and sodium arylsulfinates in neat water†

Dingyi Wang,a   Rongxing Zhang,a   Sen Lin,*a   Zhaohua Yana  and  Shengmei Guo*a  

* Corresponding authors

a College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China
E-mail: senlin@ncu.edu.cn, smguo@ncu.edu.cn

Abstract

An efficient and convenient protocol for iodine-mediated thiolation of phenols/phenylamines with sodium benzene-sulfinates in water has been achieved. In this transformation, environment-friendly conditions (including metal-free and water as solvent) are employed under air conditions, and a series of valuable thioethers are easily obtained in moderate to good yields.

Graphical abstract: Iodine-mediated thiolation of phenol/phenylamine derivatives and sodium arylsulfinates in neat water

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Article information

DOI
https://doi.org/10.1039/C5RA24351C
Article type
Communication
Submitted
18 Nov 2015
Accepted
11 Dec 2015
First published
15 Dec 2015

RSC Adv., 2015,5, 108030-108033

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Iodine-mediated thiolation of phenol/phenylamine derivatives and sodium arylsulfinates in neat water

D. Wang, R. Zhang, S. Lin, Z. Yan and S. Guo, RSC Adv., 2015, 5, 108030 DOI: 10.1039/C5RA24351C

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